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| Título: | Dibenzocycloheptatriene as end-group of Thiele and tetrabenzo-Chichibabin hydrocarbons |
Autor: | Jiménez, Vicente G.; Mayorga, Paula; Blanco, Víctor; Lloveras, Vega CSIC ORCID; Gómez-García, Carlos J.; Solomek, Tomás; Cuerva, Juan M.; Veciana, Jaume CSIC ORCID CVN; Campaña, Araceli G. | Palabras clave: | Polycyclic aromatic-hydrocarbon Aggregation-induced emission Closed-shell Singlet |
Fecha de publicación: | 28-oct-2020 | Editor: | Royal Society of Chemistry (UK) | Citación: | Chemical Communications 56(84): 12813-12816 (2020) | Resumen: | Thiele (Th) and tetrabenzo-Chichibabin (TBC) derivatives with terminal dibenzocycloheptatriene (DBHept) units were prepared. A clear correlation between their electronic and molecular structures was stablished. Insights into their closed- or open-shell ground states were gained, where particular contribution of the heptagonal carbocycles as end-groups was proved. Remarkably, a thermally accessible triplet diradical configuration was confirmed for the DBHept-TBC compound. | Versión del editor: | http://dx.doi.org/10.1039/D0CC04489J | URI: | http://hdl.handle.net/10261/233200 | ISSN: | 1359-7345 |
| Aparece en las colecciones: | (ICMAB) Artículos |
Ficheros en este ítem:
| Fichero | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
| Jimenez_ChemComm_2020_editorial.pdf | Artículo principal | 2,2 MB | Adobe PDF |  Visualizar/Abrir |
| Jimenez_ChemComm_2020_supl_editorial.pdf | Información complementaria | 8,15 MB | Adobe PDF |  Visualizar/Abrir |
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