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http://hdl.handle.net/10261/58186
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Rubio Lago, L. | - |
dc.contributor.author | Rodríguez, J.D. | - |
dc.contributor.author | García Vela, Alberto | - |
dc.contributor.author | González, M.G. | - |
dc.contributor.author | Amaral, G.A. | - |
dc.contributor.author | Bañares, Luis | - |
dc.date.accessioned | 2012-10-17T08:13:59Z | - |
dc.date.available | 2012-10-17T08:13:59Z | - |
dc.date.issued | 2011 | - |
dc.identifier | doi: 10.1039/c0cp02515a | - |
dc.identifier | issn: 1463-9076 | - |
dc.identifier.citation | Physical Chemistry Chemical Physics 13: 8186- 8194 (2011) | - |
dc.identifier.uri | http://hdl.handle.net/10261/58186 | - |
dc.description.abstract | The role of the conical intersection between the 1Q1 and 3Q0 excited states in the photodissociation of CH 3I at 304 nm is investigated drawing a comparison between the adiabatic - through direct absorption to the 3Q1 state - and non-adiabatic - via the 1Q1 → 3Q 0 conical intersection - production of I atoms in the ground 2P3/2 state. The versatility of the slice imaging technique in combination with resonance enhanced multiphoton ionization (REMPI) detection of I(2P3/2) atoms allow distinct measurements of the competing processes. The I(2P3/2) atom kinetic energy distributions (KEDs) obtained in both cases reflect inverted vibrational progressions of the ν2 umbrella mode of the CH3 co-product. The experimental results show a satisfactory agreement with multisurface wave packet calculations using a reduced dimensionality (pseudotriatomic) model carried out on the available ab initio potential energy surfaces. © 2011 the Owner Societies. | - |
dc.description.sponsorship | L.R.-L. thanks to Consejo Superior de Investigaciones Cientı´ficas (CSIC) for a JAE-DOC contract under the Unidad Asociada ‘‘Quı´mica Fı´sica Molecular’’ between Departamento de Quı´mica Fı´sica I of UCM and CSIC. J.D.R. acknowledges financial support from the Spanish Ministry of Science and Innovation (MCINN) for a FPI fellowship. G.A.A. and M.G.G. are supported by research contracts from Consolider program ‘‘Science and Applications of Ultrafast Ultraintense Lasers’’ CSD2007-00013 from MCINN. This work has been supported by the MCINN through Grants CTQ2008-02578/BQU, FIS- 2007-62002 and Consolider program ‘‘Science and Applications of Ultrafast Ultraintense Lasers’’ CSD2007-00013. | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry (UK) | - |
dc.rights | closedAccess | - |
dc.title | A slice imaging and multisurface wave packet study of the photodissociation of CH3I at 304 nm | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1039/c0cp02515a | - |
dc.date.updated | 2012-10-17T08:14:00Z | - |
dc.description.version | Peer Reviewed | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | none | - |
item.openairetype | artículo | - |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
Aparece en las colecciones: | (CFMAC-IEM) Artículos (CFMAC-IFF) Artículos |
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