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Título: | Synthesis and characterization of a plant cutin mimetic polymer |
Autor: | Heredia-Guerrero, José A. CSIC ORCID ; Heredia, Antonio; García-Segura, Rafael; Benítez, José J. CSIC ORCID | Palabras clave: | Biomimetic polymers | Biopolymer cutin | Polyaleurate | Fecha de publicación: | 16-nov-2009 | Resumen: | A mimetic polymer of plant cutin have been synthesized from 9,10,16-trihydroxyhexadecanoic (aleuritic) acid through a low temperature polycondensation reaction. Reaction conditions (solvent, catalyst, temperature, etc...) were studied and modified to optimize yield and product characteristics. The resulting polyaleurate polymer was characterized by Attenuated Total Reflection-Fourier Transform Infrared Spectroscopy (ATR-FTIR), Differential Scanning Calorimetry (DSC), X-ray Diffraction (XRD) and solid state 13C-Cross Polarization/Magic Angle Spinning Nuclear Magnetic Resonance (13C-CP/MAS NMR). Mechanical and hydrodynamic properties were also investigated. In the average, the product obtained is physically and chemically very similar to plant cutin (a hydrophobic polyester). However, a more detailed analysis of results reveals that polyaleurate framework is more rigid than natural cutin and with additional larger short-range ordered domains. Also, the synthetic polymer displays slightly different mechanical properties with respect to natural cutin. Additional hydrogen bonding within the framework of polyaleurate is considered to be responsible for such experimental observations. © 2009 Elsevier Ltd. All rights reserved. | URI: | http://hdl.handle.net/10261/344391 | DOI: | 10.1016/j.polymer.2009.10.018 | ISSN: | 00323861 |
Aparece en las colecciones: | (IHSM) Artículos |
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