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Título: | Multicomponent, functionalized HKUST-1 analogues assembled via reticulation of prefabricated metal-organic polyhedral cavities |
Autor: | Khobotov-Bakishev, Akim CSIC; Baeckmann, Cornelia von CSIC; Ortín-Rubio, Borja CSIC ORCID; Hernández-López, Laura CSIC ORCID; Cortés Martínez, Alba CSIC; Martínez Esaín, Jordi CSIC ORCID; Gándara Barragán, Felipe CSIC ORCID ; Juanhuix, Judith; Platero Prats, Ana E.; Faraudo, Jordi CSIC ORCID; Carné-Sánchez, Arnau CSIC ORCID; Maspoch, Daniel CSIC ORCID | Fecha de publicación: | 31-ago-2022 | Editor: | American Chemical Society | Citación: | Journal of the American Chemical Society 144(34): 15745-15753 (2022) | Resumen: | Metal-organic frameworks (MOFs) assembled from multiple building blocks exhibit greater chemical complexity and superior functionality in practical applications. Herein, we report a new approach based on using prefabricated cavities to design isoreticular multicomponent MOFs from a known parent MOF. We demonstrate this concept with the formation of multicomponent HKUST-1 analogues, using a prefabricated cavity that comprises a cuboctahedral Rh(II) metal-organic polyhedron functionalized with 24 carboxylic acid groups. The cavities are reticulated in three dimensions via Cu(II)-paddlewheel clusters and (functionalized) 1,3,5-benzenetricarboxylate linkers to form three- and four-component HKUST-1 analogues. | Versión del editor: | http://dx.doi.org/10.1021/jacs.2c06131 | URI: | http://hdl.handle.net/10261/283434 | DOI: | 10.1021/jacs.2c06131 | ISSN: | 0002-7863 |
Aparece en las colecciones: | (ICMAB) Artículos (CIN2) Artículos |
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Khobotov_JACS_2022_editorial.pdf | Artículo principal | 7,02 MB | Adobe PDF | Visualizar/Abrir |
Khobotov_JACS_2022_suppl_editorial.pdf | Información complementaria | 58,7 MB | Adobe PDF | Visualizar/Abrir |
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