English   español  
Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/9472
Compartir / Impacto:
Estadísticas
Add this article to your Mendeley library MendeleyBASE
Citado 2 veces en Web of Knowledge®  |  Ver citas en Google académico
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar otros formatos: Exportar EndNote (RIS)Exportar EndNote (RIS)Exportar EndNote (RIS)
Título

Studies on the Toxic Oil Syndrome: proposal of a mechanism for the thermal conversion of 3-N-phenylamino-1,2-propanediol esters into anilides under deodorisation conditions

Autor Escabrós, Jordi; Crehuet, Ramón ; Messeguer Peypoch, Ángel
Palabras clave Toxic Oil Syndrome
Deodorisation
Anilides
3-N-Phenylamino-1,2-propanediol esters
Computational studies
Reaction mechanism
Fecha de publicación 3-ene-2009
EditorElsevier
Citación Tetrahedron 65(1): 418-426 (2009)
ResumenA study on the reaction mechanism for the conversion of title esters, the species recognised as toxic biomarkers of the oil batches responsible for the Toxic Oil Syndrome, into the corresponding anilides under the thermal conditions of an oil deodorisation process was performed using experimental and computational techniques. The results obtained suggest a reaction course that includes two basic steps: an intramolecular process involving the reaction of the amine group of the diester derivative with the secondary ester of the same compound, followed by the attack of an aniline molecule to form the (E)-isomer of an imidic acid, which would finally tautomerise to give the final anilide.
Descripción 9 pages, 4 figures.-- Supplementary information (Schemes S1-S2, figure S1, tables S1-S2 and suppl. data, 4 pages) available at the paper site.
Available online 10 October 2008.
Versión del editorhttp://dx.doi.org/10.1016/j.tet.2008.09.102
URI http://hdl.handle.net/10261/9472
DOI10.1016/j.tet.2008.09.102
ISSN0040-4020
Aparece en las colecciones: (IQAC) Artículos
Ficheros en este ítem:
No hay ficheros asociados a este ítem.
Mostrar el registro completo
 



NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.