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Título: | High catalytic performance of palladium nanoparticles supported on multiwalled carbon nanotubes in alkene hydrogenation reactions |
Autor: | Cano, Manoli CSIC; Benito, Ana M. CSIC ORCID ; Maser, Wolfgang K. CSIC ORCID ; Urriolabeitia, Esteban P. CSIC ORCID | Palabras clave: | Carbon nanotubes Palladium Nanoparticles Hybrid materials Catalysis Hydrogenation reactions |
Fecha de publicación: | 26-abr-2013 | Editor: | Royal Society of Chemistry (UK) | Citación: | New Journal of Chemistry 37(7): 1968-1972 (2013) | Resumen: | The synthesis of Pd nanoparticles (Pd-NPs) supported on multiwalled carbon nanotubes (MWCNTs) and the catalytic performance of the resulting material (Pd-NPs/MWCNTs) on hydrogenation reactions are presented. Facile preparation approaches based on the decomposition of Pd precursors in the presence of MWCNTs lead to homogeneous dispersions of supported Pd-NPs with average size of 4 nm and Pd loads about 12%. The catalytic performance of this material was evaluated in hydrogenation reactions of α,β-unsaturated ketones, alkenes, cyclic di-, tri-and tetraenes, aromatic compounds, terpenes and terpenoids, resulting in very high activity offering short reaction times, high conversion rates, notable selectivity, and acceptable recyclabitiliy under mild conditions. | Descripción: | 6 pages, 2 figures, 2 tables | Versión del editor: | http://dx.doi.org/ 10.1039/C3NJ00183K | URI: | http://hdl.handle.net/10261/78954 | DOI: | 10.1039/C3NJ00183K | ISSN: | 1144-0546 | E-ISSN: | 1369-9261 |
Aparece en las colecciones: | (ICB) Artículos (ISQCH) Artículos |
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High catalytic performance of palladiumt...2013.pdf | 4,62 MB | Adobe PDF | Visualizar/Abrir |
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