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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Varela-Fernández, Alejandro | - |
dc.contributor.author | García-Yebra, Cristina | - |
dc.contributor.author | Esteruelas, Miguel A. | - |
dc.date.accessioned | 2012-07-20T10:59:37Z | - |
dc.date.available | 2012-07-20T10:59:37Z | - |
dc.date.issued | 2010 | - |
dc.identifier | doi: 10.1002/anie.201000455 | - |
dc.identifier | issn: 1433-7851 | - |
dc.identifier | e-issn: 1521-3773 | - |
dc.identifier.citation | Angewandte Chemie International Edition 49(25): 4278-4281 (2010) | - |
dc.identifier.uri | http://hdl.handle.net/10261/53651 | - |
dc.description.abstract | The wizard of Os: Regioselective osmium-catalyzed 7-endo heterocyclization of aromatic alkynols affords benzoxepines in good yields. The proposed catalytic cycle involves the key formation of osmium–vinylidene complexes via an alkynyl-hydride–osmium(IV) complex from the starting alkynol. | - |
dc.description.sponsorship | We thank the MICINN (Spain) (CTQ2008-06557, CTQ2008-00810, Consolider Ingenio 2010 (CSD2007-00006)), Xunta de Galicia (2007/XA084 and INCITE08PXIB209024PR) and Diputación General de Aragón (E35). A.V-F. thanks USC and XUGA for a predoctoral grant. C.G-Y. thanks MICINN for a Ramón y Cajal research contract. | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.rights | closedAccess | - |
dc.title | Osmium-Catalyzed 7-endo Heterocyclization of Aromatic Alkynols into Benzoxepines | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1002/anie.201000455 | - |
dc.date.updated | 2012-07-20T10:59:42Z | - |
dc.description.version | Peer Reviewed | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | none | - |
item.openairetype | artículo | - |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
Aparece en las colecciones: | (ICMA) Artículos |
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