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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Pöllnitz, Alpar | - |
dc.contributor.author | Rotar, Adina | - |
dc.contributor.author | Silvestru, Anca | - |
dc.contributor.author | Silvestru, Cristian | - |
dc.contributor.author | Kulcsar, Monika | - |
dc.date.accessioned | 2012-07-04T08:47:54Z | - |
dc.date.available | 2012-07-04T08:47:54Z | - |
dc.date.issued | 2010 | - |
dc.identifier | doi: 10.1016/j.jorganchem.2010.07.036 | - |
dc.identifier | issn: 0022-328X | - |
dc.identifier.citation | Journal of Organometallic Chemistry 695(23): 2486-2492 (2010) | - |
dc.identifier.uri | http://hdl.handle.net/10261/52775 | - |
dc.description.abstract | Diorganodiselenide [2-(Et2NCH2)C6H 4]2Se2 (1) was obtained by hydrolysis/oxidation of the corresponding [2-(Et2NCH2)C6H 4]SeLi derivative. The treatment of [2-(Et2NCH 2)C6H4]2Se2 with elemental sodium in THF resulted in [2-(Et2NCH2)C 6H4]SeNa (2). Reactions between alkali metal selenolates [2-(R2NCH2)C6H4]SeM′ (R = Me, Et; M′ = Li, Na) and MCl2 (M = Zn, Cd) in a 2:1 molar ratio resulted in the [2-(R2NCH2)C6H 4Se]2M species [R = Me, M = Zn (3), Cd (4); R = Et, M = Zn (5), Cd (6)]. The new compounds were characterized by multinuclear NMR ( 1H, 13C, 77Se, 113Cd) and mass spectrometry. The crystal and molecular structures of 1, 3 and 4 revealed monomeric species stabilized by N → Se (for 1) and N → M (for 3 and 4) intramolecular interactions. © 2010 Elsevier B.V. All rights reserved. | - |
dc.description.sponsorship | Financial support from National University Research Council and Ministry of Education and Research of Romania (Research Projects CEx 11-55/2006 and PNII-ID 2404/2008) is greatly appreciated. | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier | - |
dc.rights | closedAccess | - |
dc.title | Group 12 metal aryl selenolates. Crystal and molecular structure of [2-(Et2NCH2)C6H4]2Se 2 and [2-(Me2NCH2)C6H 4Se]2M (M = Zn, Cd) | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1016/j.jorganchem.2010.07.036 | - |
dc.date.updated | 2012-07-04T08:47:55Z | - |
dc.description.version | Peer Reviewed | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.languageiso639-1 | en | - |
item.fulltext | No Fulltext | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
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accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
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