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Título: | Hierarchical porous Fe/Ni-based bifunctional oxygen electrocatalysts for rechargeable zinc-air batteries |
Autor: | Ricciardi, Beatrice; da Silva Freitas, Williane; Mecheri, B.; Un Nisa, Khair; Montero, Jorge; Ficca, Valerio C.A.; Placidi, Ernesto; Alegre Gresa, Cinthia CSIC ORCID; D'Epifanio, Alessandra | Palabras clave: | Platinum-group-metal-free electrocatalysts Oxygen reduction reaction Oxygen evolution reaction Bifunctional catalyst Fe/Ni-based catalyst Zinc-air batteries |
Fecha de publicación: | 31-dic-2023 | Editor: | Elsevier | Citación: | Carbon 219: 118781 (2024) | Resumen: | Developing sustainable and efficient bifunctional catalysts for oxygen reduction (ORR) and evolution (OER) reactions is challenging for energy conversion and storage. This work proposes a hierarchical carbon matrix decorated with nitrogen atoms (NC) as a support for obtaining high-performance electrocatalysts based on iron and nickel (Fe/Ni@N–C). The effect of different Fe:Ni ratios and the pyrolysis conditions on the catalyst performance were investigated by combining electrochemical tests, N2-adsorption-desorption, X-ray diffraction, Transmission Electron Microscopy, and X-ray photoelectron spectroscopy. Once optimized the pyrolysis conditions and the Fe:Ni ratio, the Fe/Ni@N–C catalyst showed high bifunctional OER/ORR activity in a three-electrode cell in an alkaline environment (KOH 1 M), with an overall ΔE for the ORR-OER reaction of 0.75 V. Fe/Ni@N–C was assembled in a rechargeable zinc-air battery, resulting in an excellent electrochemical performance in terms of power density (148.5 mWcm−2) and durability, outperforming the benchmark Pt/C–RuO2. | Descripción: | 8 figures, 2 tables.-- Supplementary information available at https://ars.els-cdn.com/content/image/1-s2.0-S0008622323010266-mmc1.pdf. | Versión del editor: | http://dx.doi.org/10.1016/j.carbon.2023.118781 | URI: | http://hdl.handle.net/10261/346373 | DOI: | 10.1016/j.carbon.2023.118781 | ISSN: | 0008-6223 |
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Hierarchical porous_2024.pdf | Artículo principal | 6,02 MB | Adobe PDF | Visualizar/Abrir |
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