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http://hdl.handle.net/10261/331282
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Tan, Zhengwei | es_ES |
dc.contributor.author | Ma, Zheng | es_ES |
dc.contributor.author | Fuentes Rodríguez, Laura | es_ES |
dc.contributor.author | Liedke, Maciej O. | es_ES |
dc.contributor.author | Butterling, Maik | es_ES |
dc.contributor.author | Attallah, Ahmed G. | es_ES |
dc.contributor.author | Hirschmann, Eric | es_ES |
dc.contributor.author | Wagner, Andreas | es_ES |
dc.contributor.author | Abad, Llibertat | es_ES |
dc.contributor.author | Casañ Pastor, Nieves | es_ES |
dc.contributor.author | Lopeandía, Aitor | es_ES |
dc.contributor.author | Menéndez, Enric | es_ES |
dc.contributor.author | Sort, Jordi | es_ES |
dc.date.accessioned | 2023-07-18T10:06:24Z | - |
dc.date.available | 2023-07-18T10:06:24Z | - |
dc.date.issued | 2023-04-11 | - |
dc.identifier.citation | ACS Nano 17(7): 6973–6984 (2023) | es_ES |
dc.identifier.issn | 1936-0851 | - |
dc.identifier.uri | http://hdl.handle.net/10261/331282 | - |
dc.description.abstract | Magneto-ionics refers to the control of magnetic properties of materials through voltage-driven ion motion. To generate effective electric fields, either solid or liquid electrolytes are utilized, which also serve as ion reservoirs. Thin solid electrolytes have difficulties in (i) withstanding high electric fields without electric pinholes and (ii) maintaining stable ion transport during long-term actuation. In turn, the use of liquid electrolytes can result in poor cyclability, thus limiting their applicability. Here we propose a nanoscale-engineered magneto-ionic architecture (comprising a thin solid electrolyte in contact with a liquid electrolyte) that drastically enhances cyclability while preserving sufficiently high electric fields to trigger ion motion. Specifically, we show that the insertion of a highly nanostructured (amorphous-like) Ta layer (with suitable thickness and electric resistivity) between a magneto-ionic target material (i.e., Co3O4) and the liquid electrolyte increases magneto-ionic cyclability from <30 cycles (when no Ta is inserted) to more than 800 cycles. Transmission electron microscopy together with variable energy positron annihilation spectroscopy reveals the crucial role of the generated TaOx interlayer as a solid electrolyte (i.e., ionic conductor) that improves magneto-ionic endurance by proper tuning of the types of voltage-driven structural defects. The Ta layer is very effective in trapping oxygen and hindering O2- ions from moving into the liquid electrolyte, thus keeping O2- motion mainly restricted between Co3O4 and Ta when voltage of alternating polarity is applied. We demonstrate that this approach provides a suitable strategy to boost magneto-ionics by combining the benefits of solid and liquid electrolytes in a synergetic manner. | es_ES |
dc.description.sponsorship | Financial support by the European Union’s Horizon 2020 Research and Innovation Programme (“BeMAGIC” European Training Network, ETN/ITN Marie Skłodowska–Curie Grant No. 861145), the European Research Council (2021-ERC-Advanced “REMINDS” Grant No. 101054687), the Spanish Government (CEX2019-000917-S y PID2021-123276OB-I00, PID2020-116844RB-C21, and PDC2021-121276-C31), and the Generalitat de Catalunya (2021-SGR-00651) is acknowledged. J.S. thanks the Spanish “Fábrica Nacional de Moneda y Timbre” (FNMT) for fruitful discussions. E.M. is a Serra Húnter Fellow. Parts of this research were carried out at ELBE at the Helmholtz-Zentrum Dresden - Rossendorf e. V., a member of the Helmholtz Association. We would like to thank the facility staff for assistance. This work was partially supported by the Impulse-und Net-working fund of the Helmholtz Association (FKZ VH-VI-442 Memriox) and the Helmholtz Energy Materials Characterization Platform (03ET7015). | es_ES |
dc.description.sponsorship | With funding from the Spanish government through the ‘Severo Ochoa Centre of Excellence’ accreditation (CEX2019-000917-S). | es_ES |
dc.format | application/pdf | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/861145 | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/HE/101054687 | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de investigación Científica y Técnica y de Innovación 2017-2020/CEX2019-000917-S | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/Plan Estatal de investigación Científica y Técnica y de Innovación 2021-2023/PID2021-123276OB-I00 | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-116844RB-C21/ES/DESARROLLO DE SISTEMAS Y PROTOCOLOS MAGNETOELECTRICOS CON ALTA EFICIENCIA ENERGETICA PARA DISPOSITIVOS DE ALMACENAMIENTO DE DATOS, REGENERACION DE TEJIDOS Y ELECTROCATALISIS/ | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/Plan Estatal de investigación Científica y Técnica y de Innovación 2021-2023/PDC2021-121276-C31 | es_ES |
dc.relation.isversionof | Publisher's version | es_ES |
dc.rights | openAccess | es_ES |
dc.subject | Ion diffusion | es_ES |
dc.subject | Magneto-electricity | es_ES |
dc.subject | Magneto-ionics | es_ES |
dc.subject | Transition metal oxide | es_ES |
dc.subject | Voltage control of magnetism | es_ES |
dc.title | Regulating Oxygen Ion Transport at the Nanoscale to Enable Highly Cyclable Magneto-Ionic Control of Magnetism | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1021/acsnano.3c01105 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://doi.org/10.1021/acsnano.3c01105 | es_ES |
dc.rights.license | https://creativecommons.org/licenses/by/4.0/ | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | European Research Council | es_ES |
dc.contributor.funder | Ministerio de Ciencia e Innovación (España) | es_ES |
dc.contributor.funder | Agencia Estatal de Investigación (España) | es_ES |
dc.contributor.funder | Generalitat de Catalunya | es_ES |
dc.contributor.funder | Helmholtz Association | es_ES |
dc.contributor.funder | Ministerio de Ciencia, Innovación y Universidades (España) | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.identifier.funder | http://dx.doi.org/10.13039/501100004837 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100011033 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000781 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100002809 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100001656 | es_ES |
dc.contributor.orcid | Fuentes Rodríguez, Laura [0000-0002-8799-2369] | es_ES |
dc.contributor.orcid | Liedke, Maciej Oskar [0000-0001-7933-7295] | es_ES |
dc.contributor.orcid | Attallah, Ahmed G. [0000-0002-7759-0315] | es_ES |
dc.contributor.orcid | Casañ Pastor, Nieves [0000-0003-2979-4572] | es_ES |
dc.contributor.orcid | Menéndez, Enric [0000-0003-3809-2863] | es_ES |
dc.contributor.orcid | Sort, Jordi [0000-0003-1213-3639] | es_ES |
dc.identifier.pmid | 36972329 | - |
dc.identifier.scopus | 2-s2.0-85151371423 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/85151371423 | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.fulltext | With Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.languageiso639-1 | en | - |
Aparece en las colecciones: | (ICMAB) Artículos (CIN2) Artículos (IMB-CNM) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
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Tan_ACSNano_2023_editorial.pdf | Artículo principal | 6,9 MB | Adobe PDF | Visualizar/Abrir |
Tan_ACSNano_2023_suppl_editorial.pdf | Información complementaria | 127,27 kB | Adobe PDF | Visualizar/Abrir |
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