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Título: | Stability and Reversible Oxidation of Sub-Nanometric Cu5 Metal Clusters: Integrated Experimental Study and Theoretical Modeling |
Autor: | Buceta, David; Huseyinova, Shahana; Cuerva, Miguel; Lozano, Héctor; Giovanetti, Lisandro J.; Ramallo-López, José M.; López-Caballero, Patricia CSIC ORCID; Zanchet, Alexandre CSIC ORCID; Mitrushchenkov, Alexander O.; Hauser, Andreas W.; Barone, Giampaolo; Huck-Iriart, Cristián; Escudero, Carlos; Hernández-Garrido, Juan Carlos; Calvino, José Juan; López-Haro, Miguel; Lara Castells, María Pilar de CSIC ORCID ; Requejo, Felix Gregorio; López-Quintela, M. Arturo | Palabras clave: | Nanotechnology Oxidation Photoelectron spectroscopy X-ray absorption spectroscopy Density functional calculations |
Fecha de publicación: | 19-may-2023 | Editor: | Wiley-VCH | Citación: | Chemistry – A European Journal e202301517 (2023) | Resumen: | Sub-nanometer Metal clusters have special physical and chemical properties, significantly different from those of nanoparticles. However, there is a major concern about their thermal stability and susceptibility to oxidation. In situ X-ray Absorption spectroscopy and Near Ambient Pressure X-ray Photoelectron spectroscopy results reveal that supported Cu5 clusters are resistant to irreversible oxidation at least up to 773 K, even in the presence of 0.15 mbar of oxygen. These experimental findings can be formally described by a theoretical model which combines dispersion-corrected DFT and first principles thermochemistry revealing that most of the adsorbed O2 molecules are transformed into superoxo and peroxo species by an interplay of collective charge transfer within the network of Cu atoms and large amplitude "breathing" motions. A chemical phase diagram for Cu oxidation state of the Cu5-oxygen system is presented, clearly different from the already known bulk and nano-structured chemistry of Cu. | Descripción: | 12 pags., 6 figs. -- Cover Feature: http://hdl.handle.net/10261/348394 | Versión del editor: | https://doi.org/10.1002/chem.202301517 | URI: | http://hdl.handle.net/10261/311689 | DOI: | 10.1002/chem.202301517 |
Aparece en las colecciones: | (CFMAC-IFF) Artículos |
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Oxidation of Sub-Nanometric.pdf | Manuscrito aceptado | 2,04 MB | Adobe PDF | Visualizar/Abrir |
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