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Título: | Interrelations Of the energetics of amides and alkenes: Enthalpies of formation of N,N‐dimethyl derivatives of pivalamide, 1‐adamantylcarboxamide and benzamide, and of styrene and its α‐, trans‐β‐ and β,β‐methylated derivatives |
Autor: | Abboud, José Luis M. CSIC; Jiménez Sierra, M. Pilar CSIC ; Roux, María Victoria CSIC ; Turrión, C.; López-Mardomingo, Carmen; Podosenin, Andrew; Rogers, Donald W.; Liebman, Joel F. | Fecha de publicación: | ene-1995 | Editor: | John Wiley & Sons | Citación: | Journal of Physical Organic Chemistry 8(1): 15-25 (1995) | Resumen: | The enthalpies of formation of the condensed phase and gaseous N,N-dimethyl derivatives of pivalamide, 1-adamantylcarboxamide and benzamide were determined by combustion calorimetry and the associated enthalpies of vaporization and sublimation. The enthalpies of formation of styrene and its α-, trans-β- and β,β-methylated derivatives were determined from measurements of their enthalpies of hydrogenation in dilute hydrocarbon solution. Strain and resonance effects of amides and alkenes are discussed in terms of the exo-/endothermicity of the following reactions: equation image and in terms of the difference of enthalpies of formation of the isomeric (Z)- and E-RCHCHCH3. | Versión del editor: | http://dx.doi.org/10.1002/poc.610080105 | URI: | http://hdl.handle.net/10261/271271 | DOI: | 10.1002/poc.610080105 | Identificadores: | doi: 10.1002/poc.610080105 issn: 0894-3230 e-issn: 1099-1395 |
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