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http://hdl.handle.net/10261/271271
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dc.contributor.author | Abboud, José Luis M. | - |
dc.contributor.author | Jiménez Sierra, M. Pilar | - |
dc.contributor.author | Roux, María Victoria | - |
dc.contributor.author | Turrión, C. | - |
dc.contributor.author | López-Mardomingo, Carmen | - |
dc.contributor.author | Podosenin, Andrew | - |
dc.contributor.author | Rogers, Donald W. | - |
dc.contributor.author | Liebman, Joel F. | - |
dc.date.accessioned | 2022-06-02T08:00:11Z | - |
dc.date.available | 2022-06-02T08:00:11Z | - |
dc.date.issued | 1995-01 | - |
dc.identifier | doi: 10.1002/poc.610080105 | - |
dc.identifier | issn: 0894-3230 | - |
dc.identifier | e-issn: 1099-1395 | - |
dc.identifier.citation | Journal of Physical Organic Chemistry 8(1): 15-25 (1995) | - |
dc.identifier.uri | http://hdl.handle.net/10261/271271 | - |
dc.description.abstract | The enthalpies of formation of the condensed phase and gaseous N,N-dimethyl derivatives of pivalamide, 1-adamantylcarboxamide and benzamide were determined by combustion calorimetry and the associated enthalpies of vaporization and sublimation. The enthalpies of formation of styrene and its α-, trans-β- and β,β-methylated derivatives were determined from measurements of their enthalpies of hydrogenation in dilute hydrocarbon solution. Strain and resonance effects of amides and alkenes are discussed in terms of the exo-/endothermicity of the following reactions: equation image and in terms of the difference of enthalpies of formation of the isomeric (Z)- and E-RCHCHCH3. | - |
dc.language | eng | - |
dc.publisher | John Wiley & Sons | - |
dc.rights | closedAccess | - |
dc.title | Interrelations Of the energetics of amides and alkenes: Enthalpies of formation of N,N‐dimethyl derivatives of pivalamide, 1‐adamantylcarboxamide and benzamide, and of styrene and its α‐, trans‐β‐ and β,β‐methylated derivatives | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1002/poc.610080105 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1002/poc.610080105 | - |
dc.date.updated | 2022-06-02T08:00:11Z | - |
dc.relation.csic | Sí | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | none | - |
item.fulltext | No Fulltext | - |
item.openairetype | artículo | - |
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