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Título: | Right heterogeneous microstructure for achieving excellent thermoelectric performance in Ca0.9R0.1MnO3−δ (R = Dy, Yb) ceramics |
Autor: | Wang, Teng; Nan, pengfei; Wang, Hongchao; Su, Wenbin; Sotelo, Andres CSIC ORCID; Zhai, Jinze; Wang, Xue; Ran, Yazhou; Chen, Tingting; Wang, Chunlei | Fecha de publicación: | 2018 | Editor: | American Chemical Society | Citación: | Inorganic Chemistry 57(15): 9133-9141 (2018) | Resumen: | Perovskite manganite Ca0.9R0.1MnO3−δ (R = Dy, Yb) ceramics have been synthesized by a traditional solid-state reaction with multicalcination processes. A heterogeneous microstructure including large and small micrometer-sized grains, coherent interfaces, and oxygen defects has been formed with optimized calcination time. The carrier concentration of the third-calcined samples is enhanced approximately 3 times compared with those synthesized through conventional methods. Thus, the electrical resistivity of the third-calcined Ca0.9R0.1MnO3−δ (R = Dy, Yb) ceramic samples obviously decreases, leading to a higher power factor. Additionally, the thermal conductivity is also reduced by multiscale scattering of the heterogeneous structure. The lowest lattice thermal conductivities of Dy- or Yb-doped samples are 1.24 and 1.22 W m–1 K–1, respectively. Thus, the high thermoelectric performance for Ca0.9R0.1MnO3−δ (R = Dy, Yb) has been achieved by the multicalcination process. The highest figure of merit is almost 30% higher than that of the first-calcined samples. Therefore, a heterogeneous microstructure formed by optimized multicalcination can effectively optimize the thermoelectric performance of oxides. | Versión del editor: | https://doi.org/10.1021/acs.inorgchem.8b01163 | URI: | http://hdl.handle.net/10261/181291 | DOI: | 10.1021/acs.inorgchem.8b01163 | ISSN: | 0020-1669 | E-ISSN: | 1520-510X |
Aparece en las colecciones: | (ICMA) Artículos |
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