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Título

Nanofabrication and electrochemical characterization of self-assembled monolayers sandwiched between metal nanoparticles and electrode surfaces

AutorCea, Pilar CSIC ORCID; Martín, Santiago CSIC ORCID; González-Orive, Alejandro; Osorio, Henrry M.
Palabras claveUpper-division undergraduate
Hands-on learning/manipulatives
Graduate education/research
Interdisciplinary/multidisciplinary
Materials science
Fecha de publicación2016
EditorAmerican Chemical Society
CitaciónJournal of Chemical Education 93(8): 1441-1445 (2016)
ResumenNanoscience and nanotechnology have reached the syllabi of many upper-division undergraduate and master-level courses all over the world. There is therefore a growing need for practical exercises that illustrate the fabrication, characterization, properties, and applications of nanomaterials. Here we describe an advanced-level laboratory experiment in which students had the opportunity to fabricate surfaces modified by ordered monolayers and nanostructured materials. The surface modification was quantified by means of a quartz crystal microbalance, while the electrochemical properties of the nanoarchitectures were assessed using cyclic voltammetry experiments. Electron transfer across self-assembled monolayers mediated by gold nanoparticles was presented as a topic for discussion, and consideration of potential practical applications of the observed phenomena (catalytic and electrocatalytic processes, as well as development of optical, (opto)electronic, and photovoltaic devices with enhanced properties) was proposed as a further reading exercise.
Descripciónet al.
Versión del editorhttps://doi.org/10.1021/acs.jchemed.5b00826
URIhttp://hdl.handle.net/10261/148281
DOI10.1021/acs.jchemed.5b00826
Identificadoresdoi: 10.1021/acs.jchemed.5b00826
issn: 0021-9584
Aparece en las colecciones: (ICMA) Artículos




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