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| Título: | The biomimetic synthesis of trans-(1β-h,5α-h)-guaianolides |
Autor: | González, Antonio G.; Galindo, Antonio CSIC ORCID; Afonso, M. Mar; Mansilla, Horacio CSIC; Palenzuela, José A.; Gómez Rodríguez, Mª Ángeles; Martínez-Ripoll, Martín CSIC ORCID | Fecha de publicación: | 1988 | Editor: | Elsevier | Citación: | Tetrahedron 44(14): 4575-4584 (1988) | Resumen: | 1-epigallicin 11 underwent biomimetic cyclization to trans-(1β-H,5α-H)-guaianolide 22,the stereoespecificity of this cyclization being credited to the fact that it took place via the reacting TC conformation 27. The epimeric nor-guaianolides 15 and 17 were prepared and their rearrangements studied. The biogenetic implications of these processes are discussed. | Descripción: | 10 pages, 4 figures, 5 tables, 2 schemes. Lists of observed and calculated structure factors, final anisotrooic parameters for heavy atoms, positional and thermal parameters for H-atoms, are available from the Cambridge Crystallographic Data Centre (CCDC), University Chemical Laboratory, Lensfield Road, Cambridge CB2. |
Versión del editor: | http://dx.doi.org/10.1016/S0040-4020(01)86160-3 | URI: | http://hdl.handle.net/10261/12808 | DOI: | 10.1016/S0040-4020(01)86160-3 | ISSN: | 0040-4020 |
| Aparece en las colecciones: | (IPNA) Artículos (IQF) Artículos |
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