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http://hdl.handle.net/10261/12808
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | González, Antonio G. | en_US |
dc.contributor.author | Galindo, Antonio | en_US |
dc.contributor.author | Afonso, M. Mar | en_US |
dc.contributor.author | Mansilla, Horacio | en_US |
dc.contributor.author | Palenzuela, José A. | - |
dc.contributor.author | Gómez Rodríguez, Mª Ángeles | - |
dc.contributor.author | Martínez-Ripoll, Martín | - |
dc.date.accessioned | 2009-05-05T09:14:43Z | - |
dc.date.available | 2009-05-05T09:14:43Z | - |
dc.date.issued | 1988 | en_US |
dc.identifier.citation | Tetrahedron 44(14): 4575-4584 (1988) | en_US |
dc.identifier.issn | 0040-4020 | - |
dc.identifier.uri | http://hdl.handle.net/10261/12808 | - |
dc.description | 10 pages, 4 figures, 5 tables, 2 schemes. | - |
dc.description | Lists of observed and calculated structure factors, final anisotrooic parameters for heavy atoms, positional and thermal parameters for H-atoms, are available from the Cambridge Crystallographic Data Centre (CCDC), University Chemical Laboratory, Lensfield Road, Cambridge CB2. | - |
dc.description.abstract | 1-epigallicin 11 underwent biomimetic cyclization to trans-(1β-H,5α-H)-guaianolide 22,the stereoespecificity of this cyclization being credited to the fact that it took place via the reacting TC conformation 27. The epimeric nor-guaianolides 15 and 17 were prepared and their rearrangements studied. The biogenetic implications of these processes are discussed. | - |
dc.description.sponsorship | This work was subsidized in part by the CAICYT, Spain (Grant No 3190/84). MMA and JAP thank the MEC and CSIC, respectively, for research grants. | - |
dc.format.extent | 2373 bytes | - |
dc.format.extent | 730058 bytes | - |
dc.format.mimetype | text/plain | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier | - |
dc.rights | closedAccess | en_US |
dc.title | The biomimetic synthesis of trans-(1β-h,5α-h)-guaianolides | en_US |
dc.type | artículo | en_US |
dc.identifier.doi | 10.1016/S0040-4020(01)86160-3 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1016/S0040-4020(01)86160-3 | - |
dc.contributor.funder | Ministerio de Educación y Ciencia (España) | - |
dc.contributor.funder | Comisión Asesora de Investigación Científica y Técnica, CAICYT (España) | - |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100007272 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | none | - |
item.openairetype | artículo | - |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
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