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dc.contributor.authorGonzález, Antonio G.en_US
dc.contributor.authorGalindo, Antonioen_US
dc.contributor.authorAfonso, M. Maren_US
dc.contributor.authorMansilla, Horacioen_US
dc.contributor.authorPalenzuela, José A.-
dc.contributor.authorGómez Rodríguez, Mª Ángeles-
dc.contributor.authorMartínez-Ripoll, Martín-
dc.date.accessioned2009-05-05T09:14:43Z-
dc.date.available2009-05-05T09:14:43Z-
dc.date.issued1988en_US
dc.identifier.citationTetrahedron 44(14): 4575-4584 (1988)en_US
dc.identifier.issn0040-4020-
dc.identifier.urihttp://hdl.handle.net/10261/12808-
dc.description10 pages, 4 figures, 5 tables, 2 schemes.-
dc.descriptionLists of observed and calculated structure factors, final anisotrooic parameters for heavy atoms, positional and thermal parameters for H-atoms, are available from the Cambridge Crystallographic Data Centre (CCDC), University Chemical Laboratory, Lensfield Road, Cambridge CB2.-
dc.description.abstract1-epigallicin 11 underwent biomimetic cyclization to trans-(1β-H,5α-H)-guaianolide 22,the stereoespecificity of this cyclization being credited to the fact that it took place via the reacting TC conformation 27. The epimeric nor-guaianolides 15 and 17 were prepared and their rearrangements studied. The biogenetic implications of these processes are discussed.-
dc.description.sponsorshipThis work was subsidized in part by the CAICYT, Spain (Grant No 3190/84). MMA and JAP thank the MEC and CSIC, respectively, for research grants.-
dc.format.extent2373 bytes-
dc.format.extent730058 bytes-
dc.format.mimetypetext/plain-
dc.format.mimetypeapplication/pdf-
dc.language.isoengen_US
dc.publisherElsevier-
dc.rightsclosedAccessen_US
dc.titleThe biomimetic synthesis of trans-(1β-h,5α-h)-guaianolidesen_US
dc.typeartículoen_US
dc.identifier.doi10.1016/S0040-4020(01)86160-3-
dc.relation.publisherversionhttp://dx.doi.org/10.1016/S0040-4020(01)86160-3-
dc.contributor.funderMinisterio de Educación y Ciencia (España)-
dc.contributor.funderComisión Asesora de Investigación Científica y Técnica, CAICYT (España)-
dc.contributor.funderConsejo Superior de Investigaciones Científicas (España)-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100007272es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003339es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.cerifentitytypePublications-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.grantfulltextnone-
item.openairetypeartículo-
item.fulltextNo Fulltext-
item.languageiso639-1en-
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