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Título: | Rearrangement of carbon and nitrogen forms in peat after progressive thermal oxidation as determined by solid-state 13C-and 15N-NMR spectroscopy |
Autor: | Almendros Martín, Gonzalo CSIC ORCID ; Knicker, Heike CSIC ORCID ; González-Vila, Francisco Javier CSIC ORCID | Fecha de publicación: | nov-2003 | Editor: | Elsevier | Citación: | Organic Geochemistry 34(11): 1559-1568 (2003) | Resumen: | Peat samples subjected to thermal oxidation were studied by solid-state 13C- and 15N-NMR spectroscopy, so as to gain information on the thermal alteration of organic matter during processes such as natural fires or prescribed fires affecting soils. The 13C-NMR spectra show that heating (up to 180 s at 350 °C) increases the aromaticity of the original peat to values typical for black-carbon material, but these charred residues (at least after weight losses of ca. 25%) still contained heat-resistant alkyl carbon. The 15N-NMR spectrum of the original peat is dominated by a signal at −258 ppm, suggesting peptide-like material. In the heated samples a resonance line appearing at lower field indicates progressive formation of pyrrole- and indole-type compounds. Calculations based on weight loss, elemental composition and relative intensity distribution of the 13C- and 15N-NMR spectra demonstrate that the increasing concentrations of aromatic C-types and heterocyclic N-forms with progressive heating are not only caused by a relative enrichment concomitant with the selective thermal degradation of labile structures (mainly O-alkyl and amides) but correspond to newly-synthesised structures that were formed from aliphatic material. | Descripción: | 10 páginas, 5 figuras, 4 tablas. | Versión del editor: | http://dx.doi.org/10.1016/S0146-6380(03)00152-9 | URI: | http://hdl.handle.net/10261/55872 | DOI: | 10.1016/S0146-6380(03)00152-9 | ISSN: | 0146-6380 |
Aparece en las colecciones: | (IRNAS) Artículos |
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