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Título: | Identification and Synthesis of Leptotriene, a Unique Sesquiterpene Hydrocarbon from Males of the Leaffooted Bugs Leptoglossus zonatus and L. occidentalis |
Autor: | Millar, Jocelyn G.; Zou, Yunfan; Hall, David R.; Halloran, Sean; Pajares, J. A. CSIC; Ponce-Herrero, Laura; Shates, Tessa; Wilson, Houston; Daane, Kent M. | Palabras clave: | Carbene compounds Chemical structure Chromatography Ketones Mixtures |
Fecha de publicación: | 25-jul-2022 | Editor: | ACS Publications | Citación: | Journal of Natural Products 85(8): 2062–2070 (2022) | Resumen: | The leaffooted bugs Leptoglossus zonatus and L. occidentalis (Hemiptera: Coreidae) cause substantial damage in tree nut crops in North America and pine seed orchards in North America and Europe, respectively. Sexually mature males of both species produce a number of aldehydes, esters, and sesquiterpenes, which are hypothesized to constitute an aggregation pheromone attractive to both sexes. Among the volatiles produced by males of both species, we identified a unique sesquiterpene hydrocarbon, given the common name "leptotriene" (5), which elicited strong responses from antennae of both sexes in electroantennogram assays. Here, we report its structure and its synthesis from (-)-(E)-β-caryophyllene (1). | Descripción: | 9 Pág. | Versión del editor: | https://doi.org/10.1021/acs.jnatprod.2c00470 | URI: | http://hdl.handle.net/10261/304967 | DOI: | 10.1021/acs.jnatprod.2c00470 | ISSN: | 0163-3864 |
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