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Título: | Thermophysical properties in medium temperature range of several thio and dithiocarbamates |
Autor: | Temprado, Manuel CSIC ORCID; Roux, María Victoria CSIC ; Parameswar, Archana R.; Demchenko, Alexei V.; Chickos, James S.; Liebman, Joel F. | Palabras clave: | Dithiocarbamates DSC Fusion enthalpy Heat capacity Oxazines Oxazolines Thiazolines Thiocarbamates |
Fecha de publicación: | 8-feb-2008 | Editor: | Akadémiai Kiadó (Budapest) Springer Nature |
Citación: | Journal of Thermal Analysis and Calorimetry 91: 471- 475 (2008) | Resumen: | The present study reports a DSC study of the thio-and dithiocarbamates: 3H-benzoxazole-2-thione (2-mercaptobenzoxazole), 3H-benzothiazole-2-thione (2-mercaptobenzothiazole), thiazolidine-2-thione (2-mercapto-2-thiazoline), oxazolidine-2-thione (2-mercapto-2-oxazoline) and tetrahydro-1,3-oxazine-2-thione (5,6-dihydro-4H-1,3-oxazine-2-thiol) in the temperature interval T=268 K and the melting temperatures. Temperatures, enthalpies and entropies of fusion are reported. No solid-solid phase transitions were observed for the compounds in the temperature interval studied. The heat capacity of the compounds as a function of temperature was measured. | Versión del editor: | http://dx.doi.org/10.1007/s10973-007-8345-8 | URI: | http://hdl.handle.net/10261/271779 | DOI: | 10.1007/s10973-007-8345-8 | Identificadores: | doi: 10.1007/s10973-007-8345-8 issn: 1388-6150 e-issn: 1588-2926 |
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