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Título: | Zn-Catalyzed Direct Synthesis of 3-Iodo-1,3-dienes from ¿-Allenols |
Autor: | Toledano-Pinedo, M. CSIC ORCID; Peñín, B.; Martínez del Campo, Teresa CSIC ORCID; Almendros, Pedro CSIC ORCID | Palabras clave: | Allenes 3-iodo-1 3-dienes and zinc |
Fecha de publicación: | 13-nov-2020 | Editor: | Multidisciplinary Digital Publishing Institute | Citación: | The 24th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis | Resumen: | In recent years, the chemistry of allenes has attracted the attention of many chemists giving rise to numerous studies due to the presence of a cumulated diene in the structure of the compound. Therefore, these allenes have allowed to prepare a variety of compounds of chemical and biological interest. On the other hand, 3-iodo-1,3-dienes are interesting species in organic chemistry because of its wide reactivity. They can undergo Diels-Alder cycloaddition, palladium-catalyzed cross-coupling reactions such as Stille, Negishi, Sonogashira and carbonylation, as well as solvolysis and metallation reactions. We wish to report herein a new protocol that allows to obtain 3-iodo-1,3-dienes through a sustainable process starting from α-allenols. In this new synthetic route, zinc (II) derivatives are used as metallic promoter which are low cost and are also non-polluting species for the environment | URI: | http://hdl.handle.net/10261/230047 |
Aparece en las colecciones: | (IQOG) Comunicaciones congresos |
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