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Título: | Synthesis and structural characterization of homochiral 2D coordination polymers of zinc and copper with conformationally flexible ditopic imidazolium-based dicarboxylate ligands |
Autor: | Nicasio, Antonio I. CSIC ORCID; Montilla, Francisco; Álvarez, Eleuterio CSIC ORCID ; Colodrero, Rosario P.; Galindo, Agustín | Fecha de publicación: | 14-ene-2017 | Editor: | Royal Society of Chemistry (UK) | Citación: | Dalton Transactions 46(2): 471-482 (2017) | Resumen: | Different novel coordination polymers containing zinc, 1-4, and copper, 5-8, metals, connected via chiral imidazolium-based dicarboxylate ligands, [L], were isolated by reaction between zinc acetate or copper acetate and enantiomerically pure HL compounds. They were characterised and structurally identified by X-ray diffraction methods (single crystal and powder). These compounds are two-dimensional homochiral coordination polymers, [M(L)], in which the metal ions are coordinated by the two carboxylate groups of [L] anions in a general bridging monodentate μ-κ-O,κ-O fashion that afforded tetrahedral metal coordination environments for zinc, 1-4, and square planar for copper, 5-8, complexes. In all the compounds the 3D supramolecular architecture is constructed by non-covalent interactions between the hydrophobic parts (R groups) of the homochiral 2D coordination polymers and, in some cases, by weak C-H⋯O non-classical hydrogen bonds that provided, in general, a dense crystal packing. DFT calculations on the [L] anions confirmed their conformational flexibility as ditopic linkers and this fact makes possible the formation of different coordination polymers for four-coordinated metal centers. Preliminary studies on the Zn-catalyzed synthesis of chiral α-aminophosphonates were carried out and, unfortunately, no enantioselectivity was observed in these reactions. | Versión del editor: | http://doi.org/10.1039/C6DT03712G | URI: | http://hdl.handle.net/10261/190430 | DOI: | 10.1039/c6dt03712g | ISSN: | 1477-9226 | E-ISSN: | 1477-9234 |
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