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Título: | Electronic Delocalization in Two and Three Dimensions: Differential Aggregation in Indium “Metalloid” Clusters |
Autor: | Protchenko, Andrey V.; Urbano, Juan; Abdalla, Joseph A. B.; Campos, Jesús CSIC ORCID CVN; Vidovic, Dragoslav; Schwarz, Andrew D.; Blake, Matthew P.; Mountford, Philip; Jones, Cameron; Aldridge, Simon | Palabras clave: | Gallium Indium Boryl Metal clusters Group 13 elements |
Fecha de publicación: | 20-nov-2017 | Editor: | John Wiley & Sons | Citación: | Angewandte Chemie - International Edition 56(47): 15098-15102 (2017) | Resumen: | Reduction of indium boryl precursors to give two- and three-dimensional M−M bonded networks is influenced by the choice of supporting ligand. While the unprecedented nanoscale cluster [In(boryl)] (with an In@In@In(boryl) concentric structure), can be isolated from the potassium reduction of a bis(boryl)indium(III) chloride precursor, analogous reduction of the corresponding (benzamidinate)InBr(boryl) system gives a near-planar (and weakly aromatic) tetranuclear [In(boryl)] system. | Versión del editor: | https://doi.org/10.1002/anie.201708496 | URI: | http://hdl.handle.net/10261/190406 | DOI: | 10.1002/anie.201708496 | ISSN: | 1433-7851 | E-ISSN: | 1521-3773 |
Aparece en las colecciones: | (IIQ) Artículos |
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