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Título: | Reline aqueous solutions behaving as liquid mixtures of H-bonded co-solvents: microphase segregation and formation of co-continuous structures as indicated by Brillouin and 1H NMR spectroscopies |
Autor: | Posada, E.; López‐Salas, Nieves; Jiménez Riobóo, R. J. CSIC ORCID; Ferrer, M. Luisa CSIC ORCID; Gutiérrez, María C. CSIC ORCID ; Monte, Francisco del CSIC ORCID | Fecha de publicación: | 14-jul-2017 | Editor: | Royal Society of Chemistry (UK) | Citación: | Physical Chemistry Chemical Physics 19(26): 17103-17110 (2017) | Resumen: | Deep eutectic solvents (DESs) offer a suitable alternative to conventional solvents in terms of both performance and cost-effectiveness. Some DESs also offer certain green features, the greenness of which is notoriously enhanced when combined with water. Aqueous DES dilutions are therefore attracting great attention as a novel green medium for biotechnological processes, with the aqueous dilutions of reline-a DES composed of urea and choline chloride-being one of the most studied systems. Despite their macroscopic homogeneous appearance, both H NMR spectroscopic studies and molecular dynamics simulations have revealed the occurrence of certain dynamic heterogeneity at a microscopic molecular level. Ultrasonic measurements were also used with the aim of getting further insights but nonconclusive results were obtained. Herein, we have studied aqueous reline dilutions by Brillouin spectroscopy given its proved suitability for detecting local structure rearrangements in liquid mixtures of H-bonded co-solvents. Brillouin spectroscopy revealed the formation of a co-continuous structure resulting from local structure rearrangements and micro-segregation into aqueous and DES phases. Interestingly, there is agreement between H NMR and Brillouin spectroscopy when pointing to the DES content where microphase segregation and formation of co-continuous structures occurred. | Versión del editor: | http://doi.org/10.1039/C7CP02180A | URI: | http://hdl.handle.net/10261/189113 | DOI: | 10.1039/c7cp02180a | Identificadores: | doi: 10.1039/c7cp02180a issn: 1463-9076 e-issn: 1463-9084 |
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