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An unusual C-7 ortho ester from 6-epi-gibberellin A13. X-Ray molecular structure of gibberellene C-7 ortho ester

AuthorsFraga, Braulio M. ; González Collado, Isidro; Hernández, Melchor G.; García-Tellado, Fernando ; Perales, Áurea
Issue Date1987
PublisherRoyal Society of Chemistry (UK)
CitationJournal of the Chemical Society - Perkin Transactions I 1987: 1955-1958 (1987)
AbstractMethanolysis of the 7,19-dimethyl ester of 3-acetoxy-6-epi-gibberellin A13 20-toluene-p-sulphonic anhydride afforded an unusual C-7 ortho ester as the major product. The preparation of 3,6-epi-GA37 methyl ester and of an interesting C-19 acetal is also described.
Description4 pages, 3 figures, 1 table.
Publisher version (URL)http://dx.doi.org/10.1039/P19870001955
Appears in Collections:(IPNA) Artículos
(IQFR) Artículos
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