English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/98814
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:


Functional group directed C-H borylation

AuthorsRos, Abel ; Fernández, Rafael ; Lassaletta, José M.
Issue Date2014
PublisherRoyal Society of Chemistry (UK)
CitationChemical Society Reviews 43: 3229- 3243 (2014)
AbstractThe direct borylation of hydrocarbons via C-H activation has reached an impressive level of sophistication and efficiency, emerging as a fundamental tool in synthesis because of the versatility offered by organoboron compounds. As a remarkable particularity, the catalytic systems originally developed for these reactions are relatively insensitive to directing effects, and the regioselectivity of the borylations is typically governed by steric factors. Likely stimulated by the great synthetic potential of the expected functionalised organoboranes, however, many groups have recently focused on the development of complementary strategies for directed, site-selective borylation reactions where a directing group controls the course of the reaction. In this tutorial review, the different strategies and findings related to the development of these directed borylation reactions via C(sp2)-H or C(sp3)-H activation will be summarized and discussed. © 2014 the Partner Organisations.
Identifiersdoi: 10.1039/c3cs60418g
issn: 1460-4744
Appears in Collections:(IIQ) Artículos
Files in This Item:
File Description SizeFormat 
c3cs60418g.pdf5,1 MBAdobe PDFThumbnail
Show full item record
Review this work

Related articles:

WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.