Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/96602
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Martínez-Muñoz, A. | - |
dc.contributor.author | Monge, David | - |
dc.contributor.author | Martín-Zamora, Eloísa | - |
dc.contributor.author | Marqués-López, Eugenia | - |
dc.contributor.author | Álvarez, Eleuterio | - |
dc.contributor.author | Fernández, Rosario | - |
dc.contributor.author | Lassaletta, José M. | - |
dc.date.accessioned | 2014-05-13T11:13:36Z | - |
dc.date.available | 2014-05-13T11:13:36Z | - |
dc.date.issued | 2013 | - |
dc.identifier | doi: 10.1039/c3ob41437j | - |
dc.identifier | issn: 1477-0520 | - |
dc.identifier.citation | Organic and Biomolecular Chemistry 11: 8247- 8255 (2013) | - |
dc.identifier.uri | http://hdl.handle.net/10261/96602 | - |
dc.description.abstract | The enantioselective organocatalytic Strecker-type reaction of aliphatic N,N-dialkylhydrazones is presented. Using trimethylsilyl cyanide (TMSCN) as the cyanide source, the reaction can be efficiently catalyzed by a tert-leucine-derived bifunctional thiourea to afford the corresponding hydrazino nitriles in good to excellent yields (50-96%) and moderate to good enantioselectivities, up to 86% ee. Further transformations of the nitrile functionality allow access to useful protected hydrazino acids and imidazolidinones. Interestingly, some of the hydrazino nitriles and their derivatives could be recrystallized in high recovery, yielding essentially pure enantiomers. © 2013 The Royal Society of Chemistry. | - |
dc.publisher | Royal Society of Chemistry (UK) | - |
dc.rights | openAccess | - |
dc.title | Asymmetric organocatalytic Strecker-type reactions of aliphatic N,N-dialkylhydrazones | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1039/c3ob41437j | - |
dc.date.updated | 2014-05-13T11:13:36Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.fulltext | With Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
Aparece en las colecciones: | (IIQ) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
c3ob41437j.pdf | 974,28 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
12
checked on 08-may-2024
WEB OF SCIENCETM
Citations
11
checked on 28-feb-2024
Page view(s)
383
checked on 13-may-2024
Download(s)
323
checked on 13-may-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.