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dc.contributor.author | Palacios, Laura | - |
dc.contributor.author | Giuseppe, Andrea di | - |
dc.contributor.author | Pascal, Simon | - |
dc.contributor.author | Cunchillos, Carmen | - |
dc.contributor.author | Castarlenas, Ricardo | - |
dc.contributor.author | Pérez-Torrente, Jesús J. | - |
dc.contributor.author | Lahoz, Fernando J. | - |
dc.contributor.author | Dixneuf, Pierre H. | - |
dc.contributor.author | Oro, Luis A. | - |
dc.date.accessioned | 2013-01-28T10:33:24Z | - |
dc.date.available | 2013-01-28T10:33:24Z | - |
dc.date.issued | 2011 | - |
dc.identifier | doi: 10.1021/om2005782 | - |
dc.identifier | issn: 0276-7333 | - |
dc.identifier | e-issn: 1520-6041 | - |
dc.identifier.citation | Organometallics 30(19): 5208-5213 (2011) | - |
dc.identifier.uri | http://hdl.handle.net/10261/65225 | - |
dc.description.abstract | The first rhodium alkylidene square-planar complex stabilized by an N-heterocyclic carbene ligand, RhCl(=CHPh)(IPr)PPh3 (2; IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-carbene), has been prepared by reaction of RhCl(IPr)(PPh3)2 (1) with phenyldiazomethane and its dynamic behavior in solution studied. Treatment of 2 with alkenes results in the formation of the η2-olefin complexes RhCl(η2- CH2=CHR)(IPr)PPh3 (3, R = H; 4, R = Ph; 5, R = OEt) and new olefins arising from the coupling of the alkylidene with the alkenes, likely via a metallacyclobutane intermediate. © 2011 American Chemical Society. | - |
dc.description.sponsorship | Financial support from the Ministerio de Ciencia e Innovación (MICINN/FEDER) of Spain (Project CTQ2010-15221), the Diputación General de Aragón (E07), the ARAID Foundation under the program “Jóvenes Investigadores”, and CONSOLIDER INGENIO-2010, Projects MULTICAT (CSD2009-00050) and Factoría de Crystalización (CSD2006-0015), are gratefully acknowledged. R.C. thanks the CSIC and the European Social Fund for his Research Contract in the framework of the “Ramón y Cajal” Program. | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isversionof | Postprint | - |
dc.rights | openAccess | - |
dc.title | Synthesis of a square-planar rhodium alkylidene N-heterocyclic carbene complex and its reactivity toward alkenes | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1021/om2005782 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1021/om2005782 | - |
dc.date.updated | 2013-01-28T10:33:24Z | - |
dc.description.version | Peer Reviewed | - |
dc.contributor.funder | Ministerio de Ciencia e Innovación (España) | - |
dc.contributor.funder | Diputación General de Aragón | - |
dc.contributor.funder | ARAID Foundation | - |
dc.contributor.funder | Factoría Española de Cristalización | - |
dc.contributor.funder | European Commission | - |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100004837 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.languageiso639-1 | en | - |
item.fulltext | With Fulltext | - |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
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SynthesisSquare-Planar.pdf | 488,07 kB | Adobe PDF | Visualizar/Abrir |
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