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| Título: | Fructose-Based Proline Analogues: Exploring the Prolyl trans/cis-Amide Rotamer Population in Model Peptides |
Autor: | Cipolla, Laura; Airoldi, Cristina; Bini, David; Gregori, María CSIC ORCID; Marcelo, Filipa CSIC ORCID; Jiménez-Barbero, Jesús CSIC ORCID; Nicotra, Francesco | Palabras clave: | Peptides Peptidomimetics Carbohydrates Molecular modeling Molecular dynamics |
Fecha de publicación: | 2011 | Editor: | Wiley-VCH | Citación: | European Journal of Organic Chemistry 1:128-136 (2011) | Resumen: | A D-fructose moiety in which a D-proline ring has been engineered with a spiranic junction in the glycidic scaffold has been used as a proline mimetic. The bicyclic structure, which possesses high structural rigidity, was then included in model peptides to explore their prolyl cis/trans amide rotamer populations. Model peptide conformations were studied by molecular dynamics and NMR experiments | Descripción: | 9 páginas, 4 figuras, 2 tablas, 2 esquemas -- PAGS nros. 128-136 | Versión del editor: | http:dx.doi.org/10.1002/ejoc.201000983 | URI: | http://hdl.handle.net/10261/52101 | DOI: | 10.1002/ejoc.201000983 | ISSN: | 1434-193X | E-ISSN: | 1099-0690 |
| Aparece en las colecciones: | (CIB) Artículos |
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