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Título: | Sepiolite promotes photodegradation of pyrene under visible light |
Autor: | Marcelo, G.; Rodríguez-Pascual, Pedro; Batanero, B.; Mendicuti, F.; Pecharromán, Carlos CSIC ORCID CVN | Palabras clave: | Mechanochemisty PAHs Photocatalysis Pyrene Sepiolite |
Fecha de publicación: | 17-oct-2023 | Editor: | Elsevier BV | Citación: | Ecotoxicology and Environmental Safety 266 (2023) 115573 | Resumen: | Mechanochemistry and photocatalysis are emergent technologies for the remediation of polycyclic aromatic hydrocarbons (PAHs) in soils. In this work, mechanochemistry and photocatalysis are combined for pyrene degradation. The photodegradation of pyrene, when in contact with sepiolite under pressure application, is studied. The mechanical treatment leads to a pyrene crystal phase transformation. In this new phase, pyrene undergoes a fast photodegradation in the 320–420 nm range. We show that sepiolite is superior as a photocatalyst in pyrene degradation to TiO2, the most exploited photocatalyst. A broad physicochemical characterization is carried out to propose a mechanism in which the photoexcitation of mechanically altered pyrene leads to an electron transfer to sepiolite matrix, which triggers the PAH degradation. Finally, we want to highlight that the pyrene/sepiolite combination is a simplified system to shed light on how PAH photodegradation may occur in soils. © 2023 The Authors | Versión del editor: | https://doi.org/10.1016/j.ecoenv.2023.115573 | URI: | http://hdl.handle.net/10261/351315 | DOI: | 10.1016/j.ecoenv.2023.115573 | ISSN: | 01476513 (ISSN) |
Aparece en las colecciones: | (ICMM) Artículos |
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1-s2.0-S0147651323010771-mmc1.pdf | Material Suplementario | 507,55 kB | Adobe PDF | Visualizar/Abrir |
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