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Título: | Introducing axial chirality into mesoionic 4,4’-bis(1,2,3-triazole) dicarbenes |
Autor: | Aizpurua, Jesús M.; Sagartzazu-Aizpurua, Maialen; Monasterio, Zaira; Azcune, Itxaso; Mendicute, Claudio; Miranda, José Ignacio; García-Lecina, Eva; Altube, Ainhoa CSIC ORCID; Fratila, Raluca M. CSIC ORCID | Fecha de publicación: | 2012 | Editor: | American Chemical Society | Citación: | Organic Letters 14(7):1866-1868 (2012) | Resumen: | Mesoionic 4,4'-bis(1,2,3-triazole-5,5'-diylidene) Rh(I) complexes having a C2 chiral 4,4'-axis were accessed from 3-alkyltriazolium salts in virtually complete de. Their structure and configurational integrity were assessed by NMR spectroscopy, X-ray crystallography, and chiral HPLC. Computational analysis of the MICs involved in the reaction suggested the formation of a highly stable and unprecedented cation-carbene intermediate species, which could be evidenced experimentally by cyclic voltammetry analysis. | Versión del editor: | https://doi.org/10.1021/ol3004657 | URI: | http://hdl.handle.net/10261/344031 | DOI: | 10.1021/ol3004657 | E-ISSN: | 1523-7052 |
Aparece en las colecciones: | (INMA) Artículos |
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Org. Lett. 2012 14 1866 _ 1868 accepted.pdf | 651,41 kB | Adobe PDF | Visualizar/Abrir |
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