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Título: | Exploring Functionalities for the Development of High Thermal Stability Polypropylene-Based Dielectrics |
Autor: | Martín, Angélica; Hoyos, Mario CSIC ORCID; Gómez-Elvira González, José Manuel CSIC ORCID | Palabras clave: | Unctional polyolefins Reactive polypropylene Cross-linked polypropylene High thermal stability polypropylene Polypropylene dielectrics |
Fecha de publicación: | 2021 | Editor: | American Chemical Society | Citación: | ACS Applied Energy Mater 4 : 25−29 (2021) | Resumen: | The motivation of this study was to explore theviability of a new strategy, aimed at substantially improving boththermal and dielectric performance of polypropylene (PP),especially under oxidative conditions, by preparing in a singlestep a self-cross-linkable functionalized PP. For that purpose, anα-olefin bearing theN-alkylpyrrole moiety was copolymerized withpropylene, by using metallocene catalysis, and the obtainedmaterials thoroughly characterized. Thermal treatment at process-ing temperatures of the obtained copolymers proved that radicalchemistry associated with this function provides,per se,efficient PPcross-linking. The copolymers show high dielectric reliability andretain aflexible behavior, thus breaking new ground in the single-step preparation of high thermal stability PP-based dielectrics. | Versión del editor: | https://dx.doi.org/10.1021/acsaem.0c02760 | URI: | http://hdl.handle.net/10261/228130 | DOI: | 10.1021/acsaem.0c02760 | E-ISSN: | 2574-0962 |
Aparece en las colecciones: | (ICTP) Artículos |
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Fichero | Descripción | Tamaño | Formato | |
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Exploring Functionalities.pdf | Artículo principal | 401,75 kB | Adobe PDF | Visualizar/Abrir |
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