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http://hdl.handle.net/10261/224478
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dc.contributor.author | Corma, Avelino | - |
dc.contributor.author | Liu, Lichen | - |
dc.date.accessioned | 2020-12-07T14:40:10Z | - |
dc.date.available | 2020-12-07T14:40:10Z | - |
dc.date.issued | 2020-04 | - |
dc.identifier | doi: 10.1016/j.trechm.2020.02.003 | - |
dc.identifier | issn: 2589-5974 | - |
dc.identifier.citation | Trends in Chemistry 2(4): 383-400 (2020) | - |
dc.identifier.uri | http://hdl.handle.net/10261/224478 | - |
dc.description.abstract | Structural transformation and evolution of active metal sites can occur in metal-catalyzed reactions in both homogeneous and heterogeneous systems. Such structural changes have an important impact on the catalytic behavior, including activity, selectivity, and stability. Aiming to establish a link between homogeneous and heterogeneous catalytic systems, this review begins with a discussion on dynamic structural transformations of metal catalysts in homogeneous reactions and the corresponding implications. We then discuss the evolution of isolated metal atoms and clusters in heterogeneous catalysts during catalyst activation and under reaction conditions. Finally, strategies for stabilizing subnanometric metal species on solid supports are presented for potential industrial applications. | - |
dc.description.sponsorship | We are grateful for financial support from the EU through the European Research Council (grant ERC-AdG-2014-671093, SynCatMatch) and the Spanish government through the ‘Severo Ochoa Program’ (SEV-2016-0683). | - |
dc.language | eng | - |
dc.publisher | Elsevier BV | - |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SEV-2016-0683 | - |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/671093 | - |
dc.relation.isversionof | Publisher's version | - |
dc.rights | openAccess | - |
dc.title | Evolution of Isolated Atoms and Clusters in Catalysis | - |
dc.type | artículo de revisión | - |
dc.identifier.doi | 10.1016/j.trechm.2020.02.003 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.trechm.2020.02.003 | - |
dc.date.updated | 2020-12-07T14:40:12Z | - |
dc.rights.license | http://creativecommons.org/licenses/by-nc-nd/4.0/ | - |
dc.contributor.funder | European Research Council | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000781 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_dcae04bc | es_ES |
item.grantfulltext | open | - |
item.fulltext | With Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.openairetype | artículo de revisión | - |
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Evolution of Isolated Atoms... 1-s2.0-S2589597420300393-main.pdf | 4,95 MB | Adobe PDF | Visualizar/Abrir |
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