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Título: | Melts of single-chain nanoparticles: A neutron scattering investigation |
Autor: | Arbe, Arantxa CSIC ORCID; Rubio-Cervilla, Jon CSIC; Malo de Molina, Paula CSIC ORCID; Maiz, Jon CSIC ORCID; Pomposo, José A. CSIC ORCID; Fouquet, Peter; Prévost, Sylvain; Juranyi, Fanni; Khaneft, Marina; Colmenero de León, Juan CSIC ORCID | Fecha de publicación: | 2020 | Editor: | American Institute of Physics | Citación: | Journal of Applied Physics 127(4): 044305 (2020) | Resumen: | The impact of purely intramolecular cross-linking on the properties of a polymer melt is studied by neutron diffraction and quasielastic incoherent and coherent neutron scattering on a system composed exclusively of single-chain nanoparticles. As a reference, a parallel study is presented on the melt of the linear precursor chains’ counterpart. Associated with structural heterogeneities provoked by the internal compartmentalization due to cross-links, a dramatic slowing down of the relaxation of density fluctuations is observed at intermediate length scales. | Versión del editor: | https://doi.org/10.1063/1.5140705 | URI: | http://hdl.handle.net/10261/218494 | DOI: | 10.1063/1.5140705 | ISSN: | 0021-8979 | E-ISSN: | 1089-7550 |
Aparece en las colecciones: | (CFM) Artículos |
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meltinvesti.pdf | 2,64 MB | Adobe PDF | Visualizar/Abrir |
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