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http://hdl.handle.net/10261/189885
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Obregón, Sergio | - |
dc.contributor.author | Muñoz-Batista, Mario J. | - |
dc.contributor.author | Fernández, M. | - |
dc.contributor.author | Kubacka, Anna | - |
dc.contributor.author | Colón, Gerardo | - |
dc.date.accessioned | 2019-09-04T11:29:40Z | - |
dc.date.available | 2019-09-04T11:29:40Z | - |
dc.date.issued | 2015-12 | - |
dc.identifier.citation | Applied Catalysis B: Environmental 179: 468-478 (2015) | - |
dc.identifier.issn | 0926-3373 | - |
dc.identifier.uri | http://hdl.handle.net/10261/189885 | - |
dc.description.abstract | The influence of different TiO2 supports on the Cu active species has been studied. It was found that the photocatalytic H2 evolution is highly affected by the structural and electronic features of surface Cu species. Thus, metal dispersion and oxidation state appears strongly conditioned by the structural and surface properties of the TiO2 support. We have examined three TiO2 supports prepared by different synthetic methods; sol–gel, hydrothermal and microemulsion. In addition, we have induced structural and surface modifications by sulfate pretreatment over freshly prepared TiO2 precursors and subsequent calcination. Notably different copper dispersion and oxidation state is obtained by using these different TiO2 supports. From the wide structural and surface analysis of the catalysts we are able to propose that the occurrence of highly disperse Cu2+ species, the sample surface area as well as the crystallinity of the TiO2 support are directly related to the photocatalytic activity for H2 production reaction. | - |
dc.description.sponsorship | We acknowledge the financial support by Junta de Andalucía and MINECO-CICYT through FQM-4570, ENE2011-24412, and ENE2013-46624-C4-1-R (the latter partially financed by FEDER) projects. S. Obregón thanks CSIC for the concession of a JAE-Pre grant. A. Kubacka and M.J. Muñoz-Batista also thank Spanish MINECO for, respectively, Ramón y Cajal Post-doctoral and FIP Predoctoral fellowships | - |
dc.publisher | Elsevier | - |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2013-46624-C4-1-R | - |
dc.rights | closedAccess | - |
dc.subject | H2 evolution | - |
dc.subject | Cu–TiO2 | - |
dc.subject | Oxidation state | - |
dc.subject | Metal dispersion | - |
dc.subject | Photocatalysis | - |
dc.title | Cu–TiO2 systems for the photocatalytic H2 production: Influence of structural and surface support features | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1016/j.apcatb.2015.05.043 | - |
dc.relation.publisherversion | https://doi.org/10.1016/j.apcatb.2015.05.043 | - |
dc.date.updated | 2019-09-04T11:29:41Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.contributor.funder | Junta de Andalucía | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | - |
dc.contributor.funder | European Commission | - |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100011011 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | none | - |
item.openairetype | artículo | - |
item.fulltext | No Fulltext | - |
Aparece en las colecciones: | (ICMS) Artículos (ICP) Artículos |
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