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Título: | Synthesis of functionalized nitrogen heterocycles from β- and γ-amino acids by radical decarboxylation |
Autor: | Boto, Alicia CSIC ORCID ; Hernández, Rosendo CSIC; León, Yolanda de CSIC; Murguía, José Ramón CSIC ORCID; Rodríguez-Afonso, Abigail | Palabras clave: | Radicals Piperidines Arylpiperidines Pyrrolidines Decarboxylation Amino acids Antifungic |
Fecha de publicación: | 11-ago-2004 | Editor: | Elsevier | Citación: | Tetrahedron Letters 45(37): 6841-6845 (2004) | Resumen: | The radical decarboxylation of β- and γ-amino acids on treatment with PhI(OAc)2–I2 is a mild and efficient methodology to synthesize halogenated or oxygenated nitrogen heterocycles. The reaction was applied to the synthesis of bioactive products, such as opioid analogues, iminosugars and new antifungic agents. | Descripción: | 5 pages, 1 figure, 3 schemes.-- Printed version published Sep 6, 2004. | Versión del editor: | http://dx.doi.org/10.1016/j.tetlet.2004.07.111 | URI: | http://hdl.handle.net/10261/13457 | DOI: | 10.1016/j.tetlet.2004.07.111 | ISSN: | 0040-4039 |
Aparece en las colecciones: | (IPNA) Artículos |
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