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http://hdl.handle.net/10261/111210
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Arias, Andersson | - |
dc.contributor.author | Forniés, Juan | - |
dc.contributor.author | Fortuño, Consuelo | - |
dc.contributor.author | Martín, Antonio | - |
dc.date.accessioned | 2015-02-25T09:19:13Z | - |
dc.date.available | 2015-02-25T09:19:13Z | - |
dc.date.issued | 2013 | - |
dc.identifier | doi: 10.1016/j.ica.2013.07.048 | - |
dc.identifier | issn: 0020-1693 | - |
dc.identifier.citation | Inorganica Chimica Acta 407: 189-196 (2013) | - |
dc.identifier.uri | http://hdl.handle.net/10261/111210 | - |
dc.description.abstract | The di- and trinuclear derivatives [(RF)2Pt(μ- PPh2)2Pt(CH3CN)2], 1, [(R F)2Pt(μ-PPh2)2Pt(μ-PPh 2)2Pt(CH3CN)2], 2, (RF = C6F5) behave as synthons of di- and trinuclear fragments. Addition of azide and oxalate ions to 1 and 2, even in an excess, provides a way to isolate the tetranuclear and hexanuclear platinum complexes [NBu 4]2[{(RF)2Pt{(μ-PPh 2)2Pt}n(μ-1,1-N3)}2] (n = 1, 3; 2, 5), [NBu4]2[{(RF) 2Pt(μ-PPh2)2Pt}2(μ-C 2O4-κ2O,O′: κ 2O″,Oâ€́)}], 4, and [NBu4] 2[{(RF)2Pt(μ-PPh2) 2Pt(μ-PPh2)2Pt}2(μ-C 2O4-κ2O,O′: κ 2O″,Oâ€́)}], 6. The structures of 3-6, determined by single crystal X-ray diffraction, show a linear arrangement of the platinum centres maintained through >Pt(μ-PPh2) 2Pt> and >Pt(μ-1,1-N3)2Pt> or >Pt(μ-C2O4-κ2O,O′: κ2O″,Oâ€́)Pt> bridging fragments. Finally, addition of KCN to 2 affords the trinuclear [NBu4] 2[(RF)2Pt(μ-PPh2) 2Pt(μ-PPh2)2Pt(CN)2], 7, in which two cyanido groups are bonded to the platinum centre in a terminal way. © 2013 Elsevier B.V. All rights reserved. | - |
dc.description.sponsorship | This work was supported by the Spanish MICINN (DGPTC)/FEDER (Project CTQ2008-06669-C02-01/BQU), MINECO/FEDER (Project CTQ2012-35251) and the Gobierno de Aragón (Grupo Consolidado E21: Química Inorgánica y de los Compuestos Organometálicos). A. A. gratefully acknowledges MICINN for a FPU grant. | - |
dc.publisher | Elsevier | - |
dc.rights | closedAccess | - |
dc.subject | Single crystal X-ray diffraction | - |
dc.subject | Platinum | - |
dc.subject | Polynuclear complex | - |
dc.subject | Phosphanido ligand | - |
dc.title | From a di- and trinuclear phosphanido fragment to tetra- and hexanuclear platinum(II) complexes | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1016/j.ica.2013.07.048 | - |
dc.date.updated | 2015-02-25T09:19:13Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.contributor.funder | Ministerio de Ciencia e Innovación (España) | - |
dc.contributor.funder | European Commission | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | - |
dc.contributor.funder | Gobierno de Aragón | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100004837 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100010067 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | none | - |
item.openairetype | artículo | - |
item.fulltext | No Fulltext | - |
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