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Título: | Formation of dispersive hybrid bands at an organic-metal interface |
Autor: | González-Lakunza, N.; Fernández-Torrente, I.; Franke, K. J.; Lorente, Nicolás CSIC ORCID CVN; Arnau, Andrés CSIC ORCID; Pascual, José I. | Palabras clave: | Electrical properties of polymers; organic compounds (thin films) Surface structure of polymers and organic materials Materials science |
Fecha de publicación: | 17-abr-2008 | Editor: | American Physical Society | Citación: | Physical Review Letters 100: 156805 (2008) | Resumen: | An electronic band with quasi-one-dimensional dispersion is found at the interface between a monolayer of a charge-transfer complex (TTF-TCNQ) and a Au(111) surface. Combined local spectroscopy and numerical calculations show that the band results from a complex mixing of metal and molecular states. The molecular layer folds the underlying metal states and mixes with them selectively, through the TTF component, giving rise to anisotropic hybrid bands. Our results suggest that, by tuning the components of such molecular layers, the dimensionality and dispersion of organic-metal interface states can be engineered. | Descripción: | 4 pp.-- PACS: 73.61.Ph, 68.35.bm, 68.37.Ef | Versión del editor: | http://dx.doi.org/10.1103/PhysRevLett.100.156805 | URI: | http://hdl.handle.net/10261/7295 | DOI: | 10.1103/PhysRevLett.100.156805 | ISSN: | 0031-9007 |
Aparece en las colecciones: | (CFM) Artículos |
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Formation_of_dispersive.pdf | 2,8 MB | Adobe PDF | Visualizar/Abrir |
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