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Título: | Synthesis of d-arabinose-derived polyhydroxylated pyrrolidine, indolizidine and pyrrolizidine alkaloids. Total synthesis of hyacinthacine A2 |
Autor: | Delso, J. Ignacio CSIC ORCID; Tejero, Tomás CSIC ORCID; Goti, Andrea; Merino, Pedro CSIC ORCID | Palabras clave: | Alkaloids Pyrrolidines Nitrones |
Fecha de publicación: | feb-2010 | Editor: | Elsevier | Citación: | Tetrahedron 66(6): 1220-1227 (2010) | Resumen: | Several new polyhydroxylated alkaloids including pyrrolidines with a long side chain and 3-(hydroxymethyl) indolizidines were prepared from a common nitrone easily obtained from d-arabinose. In addition, a total synthesis of hyacinthacine A2 has been achieved in five steps and 67.7% overall yield starting from the same d-arabino-derived nitrone. All synthesized compounds have a common structural feature consisting of a pyrrolidine ring with d-arabino configuration. | Descripción: | 8 páginas, 3 figuras, 5 esquemas. | Versión del editor: | http://dx.doi.org/10.1016/j.tet.2009.12.030 | URI: | http://hdl.handle.net/10261/55894 | DOI: | 10.1016/j.tet.2009.12.030 | ISSN: | 0040-4020 |
Aparece en las colecciones: | (ICMA) Artículos |
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restringido.pdf | 21,67 kB | Adobe PDF | Visualizar/Abrir |
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