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Título: | Dynamic Hydroxyl–Yne Reaction with Phenols |
Autor: | Santos, Tanausú; Pérez-Pérez, Yaiza CSIC ORCID; Rivero, David S.; Diana-Rivero, Raquel CSIC; García-Tellado, Fernando CSIC ORCID ; Tejedor, David CSIC ORCID CVN ; Carrillo Fumero, Romen CSIC ORCID | Palabras clave: | Addition reactions aromatic compounds ethers hydrocarbons reaction dynamics |
Fecha de publicación: | 9-nov-2022 | Editor: | ACS Publications | Citación: | Organic Letters, 24(45), 8401–8405 (2022) | Resumen: | Dynamic Covalent Chemistry (DCvC) has gained increasing importance in supramolecular chemistry and materials science. Herein we prove the dynamic nature of the exchange between phenols and vinyl ethers. Exchange is fast at room temperature and under mild conditions. The equilibrium constants and the electronic effect of the phenol substituents were calculated. This novel incorporation to the DCvC toolbox could be quite useful, and as a proof it was used for the synthesis of a responsive molecular cage. | Versión del editor: | https://pubs.acs.org/doi/10.1021/acs.orglett.2c03518 | URI: | http://hdl.handle.net/10261/288745 | DOI: | 10.1021/acs.orglett.2c03518 | ISSN: | 1523-7060 | E-ISSN: | 1523-7052 |
Aparece en las colecciones: | (IPNA) Artículos |
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Dynamic-Santos_et_al-2022-Organic_Letters.docx | 461,47 kB | Microsoft Word XML | Visualizar/Abrir |
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