Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/280944
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | A new titanium building block for early–late heterometallic complexes; preparation of a new tetrameric metallomacrocycle by self assembly |
Autor: | Fandos, Rosa; Gallego, Beatriz; Otero, Antonio; Rodríguez, Antonio CSIC; Ruiz, María José; Terreros Ceballos, Pilar CSIC ; Pastor, Cesar | Fecha de publicación: | 2006 | Editor: | Royal Society of Chemistry (UK) | Citación: | Dalton Transactions (22): 2683-2690 (2006) | Resumen: | The new titanium dicarboxylate complex Cp*TiMe(OOC)2py (2) [Cp* = η5-C5Me5; (OOC)2py = 2,6-pyridinedicarboxylate] has been synthesized. The reaction of complex 2 with water renders [Cp*Ti(OOC)2py]2O (3). The molecular structure of 3 has been studied by X-ray diffraction methods. Complex 2 reacts with isocyanides to yield the respective iminoacyl derivatives Cp*Ti(η2-MeCNR)(OOC)2py [R = tBu (4), 2,6-dimethylphenyl (xylyl) (5)]. The molecular structure of complex 4 has been established by X-ray diffraction. Compound 2 has been employed as a new building block for the preparation of new early–late heterometallic compounds; it reacts with [M(µ-OH)(COD)]2 (M = Rh, Ir) to give the corresponding tetranuclear metallomacrocycle derivatives [Cp*Ti{(OOC)2py}(µ-O)M(COD)]2 [M = Rh (6); Ir (7)]. The molecular structure of 6 has been established by X-ray diffraction. | Versión del editor: | https://doi.org/10.1039/B601544A | URI: | http://hdl.handle.net/10261/280944 | DOI: | 10.1039/B601544A | E-ISSN: | 1477-9226 |
Aparece en las colecciones: | (IREC) Artículos (ICP) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
accesoRestringido.pdf | 59,24 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
WEB OF SCIENCETM
Citations
23
checked on 27-feb-2024
Page view(s)
36
checked on 06-may-2024
Download(s)
6
checked on 06-may-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.