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Título: | Pyridine vs. imidazole axial ligation on cobaloxime grafted graphene: Hydrogen evolution reaction insights |
Autor: | Sideri, Ioanna K.; Charalambidis, Georgios; Coutsolelos, Athanassios G.; Arenal, Raúl CSIC ORCID; Tagmatarchis, Nikos | Palabras clave: | Cobaloxime Hydrogen evolution reaction Axial ligation Electrocatalysis Graphene |
Fecha de publicación: | 2022 | Editor: | Multidisciplinary Digital Publishing Institute | Citación: | Nanomaterials 12(17): 3077 (2022) | Resumen: | While cobaloximes have been protagonists in the molecular (photo)catalytic hydrogen evolution reaction field, researchers originally shed light on the catalytically active metallic center. However, the specific chemical environment of cobalt, including equatorial and axial ligation, has also a strong impact on the catalytic reaction. In this article, we aim to demonstrate how pyridine vs. imidazole axial ligation of a cobaloxime complex covalently grafted on graphene affects the hydrogen evolution reaction performance in realistic acidic conditions. While pyridine axial ligation mirrors a drastically superior electrocatalytic performance, imidazole exhibits a remarkable long-term stability. | Descripción: | This article belongs to the Special Issue Nanomaterials in Catalysis for Environmental and Energy Applications. | Versión del editor: | https://doi.org/10.3390/nano12173077 | URI: | http://hdl.handle.net/10261/280634 | DOI: | 10.3390/nano12173077 | E-ISSN: | 2079-4991 |
Aparece en las colecciones: | (INMA) Artículos |
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pyridinsid.pdf | 6,81 MB | Adobe PDF | Visualizar/Abrir |
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