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http://hdl.handle.net/10261/272646
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Bohanna, Cristina | es_ES |
dc.contributor.author | Esteruelas, Miguel A. | es_ES |
dc.contributor.author | Gómez, Angel V. | es_ES |
dc.contributor.author | López, Ana M. | es_ES |
dc.contributor.author | Martínez, María-Pilar | es_ES |
dc.date.accessioned | 2022-06-16T08:38:00Z | - |
dc.date.available | 2022-06-16T08:38:00Z | - |
dc.date.issued | 1997 | - |
dc.identifier.citation | Organometallics 16(20): 4464-4468 (1997) | es_ES |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.uri | http://hdl.handle.net/10261/272646 | - |
dc.description.abstract | The five-coordinate complexes MHCl(CO)(PiPr3)2 (M = Os (1), Ru (2)) react with Na[HBpz3] in methanol at room temperature to give M(η2-HBpz3)H(CO)(PiPr3)2 (M = Os (3), Ru (4)), which in toluene under reflux evolve into M(η3-HBpz3)H(CO)(PiPr3) (M = Os (5), Ru (6)) by dissociation of triisopropylphosphine. The protonation with HBF4 of 5 and 6 in dichloromethane yields the dihydrogen complexes [M(η3-HBpz3)(η2-H2)(CO)(PiPr3)]BF4 (M = Os (7), Ru (8)), from which the dihydrogen ligand can be easily displaced by acetone to afford the solvate compounds [M(η3-HBpz3){η1-OC(CH3)2}(CO)(PiPr3)]BF4 (M = Os (9), Ru (10)). | es_ES |
dc.description.sponsorship | We thank the DGICYT (Project No. PB95-0806, Programa de Promoción General del Conocimiento) for financial support. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.rights | closedAccess | es_ES |
dc.title | Synthesis and spectroscopic characerization of new hydrido and dihydrogen complexes of osmium and ruthenium stabilized by the tris(pyrazolyl)borate ligand | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1021/om970407l | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | https://doi.org/10.1021/om970407l | es_ES |
dc.contributor.funder | Dirección General de Investigación Científica y Técnica, DGICT (España) | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.identifier.funder | http://dx.doi.org/10.13039/501100008737 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.grantfulltext | none | - |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.languageiso639-1 | en | - |
item.fulltext | No Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
Aparece en las colecciones: | (ICMA) Artículos |
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accesoRestringido.pdf | 59,24 kB | Adobe PDF | Visualizar/Abrir |
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