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| Título: | Complete characterization of a chiral lewis acid - Product complex for the enantioselective diels - Alder reaction between methacrolein and cyclopentadiene: mechanistic considerations |
Autor: | Carmona, Daniel CSIC ORCID; Lamata, M. Pilar CSIC ORCID; Viguri, Fernando CSIC; Rodríguez, Ricardo CSIC ORCID; Barba, Carmen CSIC ORCID; Lahoz, Fernando J. CSIC ORCID; Martín, M. Luisa CSIC; Oro, Luis A. CSIC ORCID; Salvatella, Luis CSIC ORCID | Fecha de publicación: | 2007 | Editor: | American Chemical Society | Citación: | Organometallics 26: 6493-6496 (2007) | Resumen: | The Diels-Alder reaction between methacrolein and cyclopentadiene catalyzed by [(η5-C5Me5)Ir{(R)-Prophos}-(methacrolein)][SbF6]2 is inhibited by the products, this feature allowing, for the first time, the spectroscopic and crystallographic characterization of the major Lewis acid-product intermediate inVolVing an enal as a dienophile. | Versión del editor: | https://doi.org/10.1021/om700717e | URI: | http://hdl.handle.net/10261/271322 | DOI: | 10.1021/om700717e | ISSN: | 0276-7333 |
| Aparece en las colecciones: | (ICMA) Artículos |
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