Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/261548
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | Synthesis, crystal structures, Hirshfeld surface analysis and physico-chemical characterization of two new ZnII and CdII halidometallates |
Autor: | Rayes, Ali; Moncer, Manel; Ara, Irene CSIC; Dege, Necmi; Ayed, Brahim | Fecha de publicación: | 2021 | Editor: | Springer Nature | Citación: | Journal of Materials Science: Materials in Electronics 32: 10890-10905 (2021) | Resumen: | Two new organic–inorganic hybrid materials, based on 1,3-CycloHexaneBis-(Methyl Amine), abbreviated CHBMA, namely (H2CHBMA)ZnCl4·2H2O (CP1) and (H2CHBMA)CdI4·2H2O (CP2), have been synthesized under mild conditions in acidic media and characterized by single-crystal X-ray diffraction, spectroscopic techniques (13C NMR, FTIR, RAMAN) and thermal analysis. The crystal structures of the two compounds were solved by single-crystal X-ray diffraction methods. Both compounds show a 3-dimensional supramolecular structure directed by various interactions between tetrahalidometallate anions (ZnCl42−, CdI42−), water molecule and organic cations (H2CHBMA)2+. For both compounds, the cyclohexane ring of the template cation is in a chair conformation with the methylammonium substituent in the equatorial positions and the two terminal ammonium groups in a cis conformation but with two different orientations (upward for CP1 and downward for CP2) which influences the supramolecular architecture of the two structures. Hirshfeld surface analysis and the associated two-dimensional finger print plots were used to explore and quantify the intermolecular interactions in the crystals. | Versión del editor: | https://doi.org/10.1007/s10854-021-05747-3 | URI: | http://hdl.handle.net/10261/261548 | DOI: | 10.1007/s10854-021-05747-3 | E-ISSN: | 1573-482X |
Aparece en las colecciones: | (ISQCH) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
synthesihallo.pdf | 2,76 MB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
5
checked on 05-may-2024
WEB OF SCIENCETM
Citations
4
checked on 14-feb-2024
Page view(s)
25
checked on 07-may-2024
Download(s)
69
checked on 07-may-2024
Google ScholarTM
Check
Altmetric
Altmetric
Este item está licenciado bajo una Licencia Creative Commons