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Título: | Fast CO2 hydrogenation to formic acid catalyzed by an Ir(PSiP) pincer hydride in a DMSO/water/ionic liquid solvent system |
Autor: | Webber, Rodrigo; Qadir, Muhammad I.; Sola, Eduardo CSIC ORCID CVN; Martín, Marta CSIC ORCID; Suárez, Elizabeth CSIC ORCID; Dupont, Jairton | Palabras clave: | Ionic liquids Solvent-cage CO2 hydrogenation Formic acid Iridium |
Fecha de publicación: | 2020 | Editor: | Elsevier | Citación: | Catalysis Communications 146: 106125 (2020) | Resumen: | Complex [IrClH{κP,P,Si-Si(Me)(C6H4–2-PiPr2)2}] (1) showed a remarkable catalytic activity for CO2 hydrogenation in a DMSO/H2O solvent system incorporating 1,2-dimethyl-3-butylimidazolium acetate ionic liquid (IL), producing 0.94 M formic acid with initial TOFs up to 1432 h−1 (CO2/H2 = 20/40 bar, 30 °C). While the hydrogenation outcome followed dependences upon gas composition, pressure and temperature similar to those of other efficient systems in DMSO/H2O, the kinetic dependence upon catalyst loading revealed non-linear effects suggestive of relevant IL-catalyst interactions. NMR speciation studies identified two major complexes, [Ir(OCHO)(H){κP,P,Si-Si(Me)(C6H4–2-PiPr2)2}] (2) and [Ir(H)2{κP,P,Si-Si(Me)(C6H4–2-PiPr2)2}(DMSO)] (3), potentially responsible for catalytic cycling though inactive outside the current solvent system. | Versión del editor: | https://doi.org/10.1016/j.catcom.2020.106125 | URI: | http://hdl.handle.net/10261/233103 | DOI: | 10.1016/j.catcom.2020.106125 | ISSN: | 1566-7367 |
Aparece en las colecciones: | (ISQCH) Artículos |
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