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| Título: | The chemical and microbiological synthesis of 14-hydroxy-gibberellins |
Autor: | Fraga, Braulio M. CSIC; García-Tellado, Fernando CSIC ORCID ; González, Pedro; Hernández, Melchor G.; Hanson, James R. | Fecha de publicación: | 1992 | Editor: | Elsevier | Citación: | Tetrahedron 48(39): pp. 8491-8504 (1992) | Resumen: | Gibberellic acid has been transformed into 14B-hydroxy-gibberellin A7 methyl ester via the rearrangement of an epoxy-beyergibberellin intermediate using a titanium-amide complex. The diterpene ent-beyer-15-en-19-ol has been transformed by chemical methods into ent-14a,19-dihydroxy-kaur-16-ene. The biotransformation of this compound with the fungus Gibberella fujokuroi gave 14B-hydroxy-gibberellin A7, ent 7a,14a,19-trihydroxy-kaur-16-ene and ent-6a,7a,14a-trihydroxy-kaur-16-en-oic acid. A minor gibberellin 14B-hydroxy-GA14 was identified by GC-MS. | URI: | http://hdl.handle.net/10261/21871 | ISSN: | 0040-4020 |
| Aparece en las colecciones: | (IPNA) Artículos |
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| TET-1992-48-8491.pdf | 410,75 kB | Adobe PDF |  Visualizar/Abrir |
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