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http://hdl.handle.net/10261/21460
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Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Fraga, Braulio M. | - |
dc.contributor.author | González, Pedro | - |
dc.contributor.author | Guillermo, Ricardo | - |
dc.contributor.author | Hernández, Melchor G. | - |
dc.date.accessioned | 2010-02-23T09:54:44Z | - |
dc.date.available | 2010-02-23T09:54:44Z | - |
dc.date.issued | 1998 | - |
dc.identifier.citation | Tetrahedron 54: pp. 6159-6168 (1998) | en_US |
dc.identifier.issn | 0040-4020 | - |
dc.identifier.uri | http://hdl.handle.net/10261/21460 | - |
dc.description.abstract | The microbiological transformations of jhanol (18-hydroxymanoyl oxide) and jhanidiol (1$,18-dihydroxymanoyl oxide) with the fungus Gibberella fujikurai have been studied. In the biotransformation of the first compound there exists a preference for hydroxylation at C-1(a) and in lower yield at C-11(a or $), while in that of the second, which possesses a l$-hydroxylation , the main reaction observed is the oxidation of this l$-hydroxyl to an oxo group. This product is then mainly reduced to the lot-alcohol or, in minor yield, hydroxylated at C-11($), C-6($) and C-2(a). The fungal epimerization of a hydroxyl group as occurs in the biotransformation of the la-alcohol of jhanidiol to the 1a-alcohol, is a very rrare process. | en_US |
dc.description.sponsorship | This work has been supported by the DGES, Ministry of Education an Culture, Spain. | en_US |
dc.format.extent | 287568 bytes | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier | en_US |
dc.rights | closedAccess | en_US |
dc.title | The biotransformation of manoyl oxide derivatives by Gibberella fujikuroi: the fungal epimerization of an alcohol group | en_US |
dc.type | artículo | en_US |
dc.description.peerreviewed | Peer reviewed | en_US |
dc.contributor.funder | Ministerio de Educación y Cultura (España) | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.languageiso639-1 | en | - |
item.grantfulltext | none | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
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