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Título: | A helical, aromatic, peptide nanotube |
Autor: | Marco Crisma, Marco; Toniolo, Claudio; Royo, Soledad; Jiménez, Ana I. CSIC ORCID; Cativiela, Carlos CSIC ORCID | Fecha de publicación: | 18-nov-2006 | Editor: | American Chemical Society | Citación: | Organic Letters 8(26): 6091–6094 (2006) | Resumen: | The self-assembly in the crystal state of the terminally protected, linear dipeptide Boc-(S,S)c3diPhe-(R,R)c3diPhe-NHiPr (1) through intermolecular hydrogen bonds leads to the formation of a supramolecular helix of large diameter (18 Å), internally decorated with phenyl rings. As a result, a hollow helical channel large enough to accommodate guest molecules is observed. This supramolecular structure differs from previous examples of peptide nanotubes. Compound 1 incorporates a highly restricted cyclopropane phenylalanine analogue (c3diPhe) with remarkable conformational properties. | Descripción: | 4 pages, 3 figures, 2 tables. | Versión del editor: | http://dx.doi.org/10.1021/ol062600u | URI: | http://hdl.handle.net/10261/19489 | DOI: | 10.1021/ol062600u | ISSN: | 1520-5126 |
Aparece en las colecciones: | (ICMA) Artículos |
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