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| Título: | Hydroxylamine oxygen as nucleophile in palladium(0)-and palladium(II)-catalyzed allylic alkylation : A novel access to isoxazolidines |
Autor: | Merino, Pedro CSIC ORCID ; Tejero, Tomás CSIC ORCID; Mannucci, Vanni | Palabras clave: | Palladium Ring closure Hydroxylamines Allyl complexes Isoxazolidines |
Fecha de publicación: | abr-2007 | Editor: | Thieme | Citación: | Synlett (6): 944-948 (2007) | Resumen: | In search for novel heterocyclization processes, the intramolecular Pd-mediated allylic alkylation of homoallyl hydroxylamines is described. Depending on both the reaction conditions and the substrates, cis- or trans-3-substituted-5-vinyl isoxazolidines are preferentially obtained. The corresponding starting materials for the cyclization step are readily obtained through cross-metathesis of the easily accessible unsubstituted homoallyl hydroxylamines. | Descripción: | 5 pages.-- et al. | Versión del editor: | http://dx.doi.org/10.1055/s-2007-973868 | URI: | http://hdl.handle.net/10261/19243 | DOI: | 10.1055/s-2007-973868 | ISSN: | 0936-5214 | E-ISSN: | 1437-2096 |
| Aparece en las colecciones: | (ICMA) Artículos |
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| accesoRestringido.pdf | 15,38 kB | Adobe PDF |  Visualizar/Abrir |
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